| Spain
1964 | 1962-11-01
| 1962-11-25
| 1963-05-30
| 1963-10-30
| 1964-03-11
| 1964-04-08
| 1964-06-17
| 1964-06-21 | European Championship W/D/L: 6/1/1 | |||||||||
| Romania
| Romania
| Northern Ireland
| Northern Ireland
| Ireland
| Ireland
| Hungary
| Soviet Union
| N | Appearances | Starts | Goals | Assists
| |||||
H | A | H | A | H | A | H | H
| |||||||||||
6-0
| 1-3
| 1-1
| 1-0
| 5-1
| 2-0
| 2-1
| 2-1
| |||||||||||
| José Ángel Iribar | G | ✓ | ✓ | ✓ | ✓ | 4 | 4 | 4 | 0 | 0 | ||||||||
| Vicente Train | G | ✓ | ✓ | ✓ | 3 | 3 | 3 | 0 | 0 | |||||||||
| Pepin | G | ✓ | 1 | 1 | 1 | 0 | 0 | |||||||||||
| Salvador Sadurní | G | 2 | 0 | |||||||||||||||
| Feliciano Rivilla | D | ✓ | ✓ | ✓ | ✓ | ✓ | ✓ | ✓ | 7 | 7 | 7 | 0 | 0 | |||||
| Isacio Calleja | D | ✓ | ✓ | ✓ | ✓ | ✓ | ✓ | 6 | 6 | 6 | 0 | 0 | ||||||
| Ferran Olivella | D | ✓ | ✓ | ✓ | ✓ | ✓ | 5 | 5 | 5 | 0 | 0 | |||||||
| Rodri | D | ✓ | ✓ | 2 | 2 | 2 | 0 | 0 | ||||||||||
| Pachín | D | ✓ | ✓ | 2 | 2 | 2 | 0 | 0 | ||||||||||
| Severino Reija | D | ✓ | ✓ | 4 | 2 | 2 | 0 | 0 | ||||||||||
| Luis Echeberría | D | ✓ | 1 | 1 | 1 | 0 | 0 | |||||||||||
| Gallego | D | 2 | 0 | |||||||||||||||
| Ignacio Zoco | M | ✓ | ✓ | ✓ | ✓ | ✓ | 5 | 5 | 5 | 0 | 0 | |||||||
| Chus Pereda | M | ✓ | ✓ | ✓ | ✓ | ✓ | 5 | 5 | 5 | 2 | 0 | |||||||
| Josep Fusté | M | ✓ | ✓ | ✓ | ✓ | 4 | 4 | 4 | 1 | 1 | ||||||||
| Luis Suárez | M | ✓ | ✓ | ✓ | 3 | 3 | 3 | 0 | 1 | |||||||||
| Paquito | M | ✓ | ✓ | ✓ | 5 | 3 | 3 | 0 | 0 | |||||||||
| Jesús Glaría | M | ✓ | ✓ | 2 | 2 | 2 | 0 | 0 | ||||||||||
| Adelardo | M | ✓ | ✓ | 2 | 2 | 2 | 0 | 0 | ||||||||||
| Félix Ruiz | M | ✓ | ✓ | 2 | 2 | 2 | 0 | 0 | ||||||||||
| Juan Manuel Villa | M | ✓ | ✓ | 2 | 2 | 2 | 0 | 0 | ||||||||||
| Luis del Sol | M | ✓ | 3 | 1 | 1 | 0 | 0 | |||||||||||
| Amancio | F | ✓ | ✓ | ✓ | ✓ | ✓ | 5 | 5 | 5 | 4 | 0 | |||||||
| Marcelino | F | ✓ | ✓ | ✓ | ✓ | 4 | 4 | 4 | 3 | 3 | ||||||||
| Carlos Lapetra | F | ✓ | ✓ | ✓ | ✓ | 4 | 4 | 4 | 0 | 1 | ||||||||
| Enrique Collar | F | ✓ | ✓ | ✓ | 3 | 3 | 3 | 1 | 1 | |||||||||
| Paco Gento | F | ✓ | ✓ | ✓ | 3 | 3 | 3 | 1 | 0 | |||||||||
| José Veloso | F | ✓ | ✓ | 2 | 2 | 2 | 2 | 1 | ||||||||||
| Vicente Guillot | F | ✓ | ✓ | 2 | 2 | 2 | 3 | 2 | ||||||||||
| Delio Morollón | F | ✓ | 1 | 1 | 1 | 0 | 0 | |||||||||||
| José Zaldúa | F | ✓ | 1 | 1 | 1 | 0 | 0 | |||||||||||
| Peru Zaballa | F | ✓ | 3 | 1 | 1 | 2 | 1 | |||||||||||
| Manager: | José Villalonga
| |||||||||||||||||