| Spain
1966 | 1965-05-05
| 1965-10-27
| 1966-07-13
| 1966-07-15
| 1966-07-20 | World Cup W/D/L: 2/0/3 | |||||||||
| Ireland
| Ireland
| Argentina
| Switzerland
| Germany
| In squad | Appearances | Starts | Yellow cards | Own goals | Goals
| ||||
A | H | A | H | A
| |||||||||||
0-1
| 4-1
| 1-2
| 2-1
| 1-2
| |||||||||||
| José Ángel Iribar | G | ✓ | ✓ | ✓ | ✓ | 4 | 4 | 4 | 0 | 1 | 0 | ||||
| Antonio Betancort | G | ✓ | ∘ | 2 | 1 | 1 | 0 | 0 | 0 | ||||||
| Miguel Reina | G | ∘ | ∘ | ∘ | 3 | 0 | |||||||||
| Ignacio Zoco | D | ✓ | ✓ | ✓ | ✓ | ✓ | 5 | 5 | 5 | 0 | 0 | 0 | |||
| Severino Reija | D | ✓ | ✓ | ∘ | ✓ | ✓ | 5 | 4 | 4 | 0 | 0 | 0 | |||
| Gallego | D | ✓ | ✓ | ✓ | 3 | 3 | 3 | 0 | 0 | 0 | |||||
| Manuel Sanchís | D | ✓ | ✓ | ✓ | 3 | 3 | 3 | 0 | 0 | 1 | |||||
| Ferran Olivella | D | ✓ | ✓ | ∘ | ∘ | ∘ | 5 | 2 | 2 | 0 | 0 | 0 | |||
| Feliciano Rivilla | D | ✓ | ✓ | ∘ | ∘ | ∘ | 5 | 2 | 2 | 0 | 0 | 0 | |||
| Eladio Silvestre | D | ✓ | ∘ | ∘ | 3 | 1 | 1 | 0 | 0 | 0 | |||||
| Luis Suárez | M | ✓ | ✓ | ✓ | ∘ | 4 | 3 | 3 | 0 | 0 | 0 | ||||
| Jesús Glaría | M | ✓ | ✓ | ∘ | ∘ | ✓ | 5 | 3 | 3 | 1 | 0 | 0 | |||
| Pirri | M | ✓ | ✓ | ∘ | 3 | 2 | 2 | 0 | 0 | 1 | |||||
| Luis del Sol | M | ✓ | ✓ | ∘ | 3 | 2 | 2 | 0 | 0 | 0 | |||||
| Chus Pereda | M | ✓ | 1 | 1 | 1 | 0 | 0 | 3 | |||||||
| Josep Fusté | M | ∘ | ∘ | ✓ | 3 | 1 | 1 | 0 | 0 | 1 | |||||
| José Ufarte | F | ✓ | ✓ | ✓ | ∘ | ∘ | 5 | 3 | 3 | 0 | 0 | 0 | |||
| Marcelino | F | ✓ | ✓ | ∘ | ∘ | ✓ | 5 | 3 | 3 | 0 | 0 | 0 | |||
| Carlos Lapetra | F | ✓ | ✓ | ∘ | ∘ | ✓ | 5 | 3 | 3 | 0 | 0 | 1 | |||
| Paco Gento | F | ✓ | ✓ | ∘ | 3 | 2 | 2 | 0 | 0 | 0 | |||||
| Joaquín Peiró | F | ✓ | ✓ | ∘ | 3 | 2 | 2 | 0 | 0 | 0 | |||||
| Adelardo | F | ✓ | ∘ | ∘ | ✓ | 4 | 2 | 2 | 0 | 0 | 0 | ||||
| Amancio | F | ∘ | ✓ | ✓ | 3 | 2 | 2 | 0 | 0 | 1 | |||||
| Vicente Guillot | F | ✓ | 1 | 1 | 1 | 0 | 0 | 0 | |||||||
| Manager: | José Villalonga | ||||||||||||||
| ‹1964 | 1968› | ||||||||||||||